• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A piece (300) of oxide / oxide composite material comprises a fibrous reinforcement (310) consisting of a plurality of warp yarn layers (312) and weft yarn layers (311) bonded together in three-dimensional weave, the gaps between the reinforcement wires being filled with a refractory oxide matrix (320). The piece is characterized in that the fibrous reinforcement has a weave chosen from one of the following weaves: interlock, multi-fabric, multi-satin and multi-twill, and a warp and weft contexture of between 4 and 20 threads. / cm. The fiber reinforcement furthermore has a fiber volume content of between 40% and 51%.
    公开号:FR3017866A1
    申请号:FR1451447
    申请日:2014-02-24
    公开日:2015-08-28
    发明作者:Pascal Diss；Eric Bouillon；Eric Lavasserie
    申请人:Herakles SA；
    IPC主号:
    专利说明:

    [0001] BACKGROUND OF THE INVENTION The present invention relates to a method for manufacturing a composite material part of the oxide / oxide type, that is to say comprising a fibrous reinforcement formed from refractory oxide fibers densified by a matrix also in refractory oxide.
    [0002] For the most part, the parts made of oxide / oxide composite material are produced in two ways: - production of a fibrous texture by stacking two-dimensional layers of oxide fiber fabric and impregnation of the texture with a suspension containing oxide fillers, the filled preform is then subjected to sintering, - production of a fibrous texture by winding oxide fiber son previously immersed in suspension containing oxide charges, the filled preform then being subjected to sintering. However, the mechanical characteristics of the oxide / oxide composite materials obtained by these manufacturing processes are limited in certain directions. In particular, these materials have low shear strength. The production of fibrous textures obtained by three-dimensional weaving between continuous warp and weft yarns makes it possible to increase the mechanical strength of the material. In this case, only the processes using a pressure gradient, such as injection molding processes known as "RTM" or submicron powder suction called "APS" allow to penetrate a loaded suspension in the fibrous texture whose thickness can reach several tens of 30 millimeters depending on the intended applications. The fiber volume ratio of oxide / oxide composite materials is one of the fundamental parameters to consider in achieving the final mechanical properties of the material. Therefore, when developing an oxide / oxide composite material, the fibrous texture must be compacted using a specific tooling. During the tooling drying step, a network of cracks is formed in the matrix present between the wires. This network of cracks leads to an expansion of the preform impregnated during demolding, which causes a significant reduction in the mechanical properties of the material in the final stage.
    [0003] One known way to overcome this expansion is to add in the starting slurry an organic binder, for example polyvinyl acid (PVA), which contributes to the cohesion of the system after drying the preform by preventing the phenomenon of expansion described above.
    [0004] To obtain high mechanical characteristics in a single impregnation step, it is necessary to use a slurry comprising a sufficient percentage by volume of charges. In this case, the addition of an organic binder modifies the behavior of the slip. This changes from a Newtonian behavior (viscosity independent of the flow velocity) to a rheofluidifying behavior (viscosity dependent on the flow velocity). This phenomenon causes the appearance of heterogeneity of composition in the material during APS preparation. More precisely, at the global scale of the material, the poor control of the flow of the suspension in the fibrous texture leads to the appearance of a composition gradient (fiber / matrix ratio) in the thickness of the material. More locally in the material, porosities whose size and distribution are not controlled are formed after stabilization of the charges by sintering.
    [0005] OBJECT AND SUMMARY OF THE INVENTION The object of the present invention is to overcome the aforementioned drawbacks and to propose a solution that makes it possible to have parts made of an oxide / oxide composite material produced by APS, in a single impregnation step, without requiring the use of an additional organic binder, the parts comprising a reinforcement obtained by three-dimensional weaving and having improved mechanical properties compared to the parts of the prior art.
    [0006] For this purpose, the invention proposes a piece of oxide / oxide composite material comprising a fibrous reinforcement consisting of a plurality of layers of warp yarns and layers of weft yarns bonded together in three-dimensional weave, the spaces present between the son of the reinforcement being filled with a matrix of refractory oxide, characterized in that the fibrous reinforcement has a weave selected from one of the following weaves: interlock, multi-fabric, multi-satin and multi-twill, and a texture in warp and weft between 4 threads / cm and 20 threads / cm, and in that the fibrous reinforcement has a fiber volume of between 40% and 51%. With a fibrous reinforcement having the characteristics defined above, and taking care to adjust the volume ratio of fibers to the chosen texture variant, the spaces present between the reinforcement threads have dimensions less than five times the maximum section threads of the fibrous reinforcement. By thus limiting the size of the spaces present between the wires, the size of the matrix blocks present in the material is limited so that each matrix block has no dimension which is greater than five times the maximum section of the reinforcement wires. The Holder found that by limiting in this way the size of the matrix blocks in the oxide / oxide material, it was possible to prevent the occurrence of cracks therein. The piece of oxide / oxide composite material has, therefore, improved mechanical properties. According to a particular aspect of the piece of the invention, the latter has, in monotonic traction, at ambient temperature and in the warp direction: a modulus of elasticity of between 120 GPa and 170 GPa, at least one breaking strain; equal to 0.35%, - a breaking stress greater than 250 MPa. The fibers of the fibrous reinforcement may be formed of fibers consisting of one or more of the following materials: alumina, mullite, silica, an aluminosilicate and a borosilicate. The matrix material may be chosen from: alumina, mullite, silica, an aluminosilicate and an aluminophosphate. The matrix may optionally be doped with one or more materials making it possible to add specific functions to the final material of the part.
    [0007] The invention also relates to a method of manufacturing a piece of oxide / oxide composite material comprising the following steps: - formation of a fibrous texture by three-dimensional weaving of refractory oxide strands, - compaction of the fibrous texture, - placement of one side of the fibrous texture of a slip containing a submicron powder of refractory oxide particles, - establishing a pressure difference to force the slip to pass through the fibrous texture, - filtration of the slip liquid having passed through the texture fibrous material for retaining the powder of refractory oxide particles within said texture, and - drying the filled preform, - sintering the submicron powder of refractory oxide particles to form a refractory oxide matrix in the preform, characterized in that, during the step of forming the fibrous texture, the yarns are woven according to a chosen weave weave e among one of the following armor: interlock, multi-canvas, multi-satin and multi-twill, with a warp and weft contexture between 4 threads / cm and 20 threads / cm, and what, after the step of compaction, said fibrous texture has a fiber volume of between 40% and 51%.
    [0008] Thus, parts made of oxide / oxide composite material with 3D woven reinforcement are perfectly homogeneous throughout their volume and which do not have cracks or porosities likely to degrade the mechanical properties of the part. The yarns of the preform may be fiber yarns made of one or more of the following materials: alumina, mullite, silica, aluminosilicate, and borosilicate. The submicron particles may be of a material chosen from: alumina, mullite, silica, an aluminosilicate and an alminophosphate, with possibly additional fillers making it possible to add functions to the material of the part.
    [0009] BRIEF DESCRIPTION OF THE DRAWINGS Other characteristics and advantages of the invention will emerge from the following description of particular embodiments of the invention, given by way of non-limiting examples, with reference to the appended drawings, in which: FIG. 1 illustrates a plane of three-dimensional interlock weave according to one embodiment of the fibrous texture of the invention; FIG. 2 illustrates a plane of a three-dimensional multi-web weave according to one embodiment; FIG. 3 illustrates a plane of a three-dimensional multi-satin weave according to one embodiment of the fibrous texture of the invention; FIG. 4 illustrates a plan of multi-twill three-dimensional weave in accordance with one embodiment of the fibrous texture of the invention; FIG. 5 is a schematic view showing the infiltration of a woven fabric; fibrous extext with APS-refractory oxide particles; FIG. 6 is a microscopic photograph of a sectional section of an oxide / oxide composite material manufactured according to the prior art, FIGS. 7A, 7B and FIG. 7C are microscopic photographs of a piece of oxide / oxide composite material according to the invention. DETAILED DESCRIPTION OF EMBODIMENTS The method of manufacturing an oxide / oxide composite material part according to the present invention starts with the production of a fibrous texture intended to form the reinforcement of the part. According to the invention, the fiber texture is made by three-dimensional weaving between a plurality of warp yarns and a plurality of weft yarns, the warp yarn layers being bonded together by weft yarns in a corresponding three-dimensional weave. to a weave selected from one of the following weaves: interlock, multi-fabric, multi-satin and multi-twill, and with a warp and weft pattern of between 4 threads / cm and 20 threads / cm, the texture as well as The resulting product is then compacted to have a fiber volume of between 40% and 51%. These characteristics of the fibrous texture make it possible to ensure that it will not have spaces between the threads of a dimension greater than 5 times the maximum section of the threads. Thus, once the matrix is formed within the texture, the matrix blocks present between the texture threads will have dimensions all of less than 5 times the maximum section of the threads, which makes it possible to prevent the appearance of cracks. in the final material of the piece. By "matrix block" is meant here any continuous portion of matrix located between two or more son. By "size of a matrix block" is meant any length, width, depth, thickness, height, or diameter of a matrix block and, even more generally, any size that can be measured. in a straight direction. By "contexture" is meant here the number of threads per unit length in the warp and weft directions. By "three-dimensional weaving" or "3D weaving" is meant here a weaving mode whereby at least some of the warp yarns bind weft yarns on several weft layers. Throughout the following text and in all the drawings, it is mentioned and represented by convention and convenience, that it is the warp yarns which are deviated from their paths for gripping weft yarns of a weft layer or multiple layers of frames. However, a reversal of roles between warp and frame is possible, and should be considered as also covered by the claims. By "weave or interlock fabric" is meant herein a 3D weave weave in which each layer of warp yarn binds several layers of weft yarns with all the yarns of the same warp column having the same movement in the plane of the weave. 'armor. Figure 1 is an 8-plane view of an interlock weave with 7 layers of C 1 and CTI 8-layer wire. weft son Ti. In the illustrated interlock armor, a layer C n of weft yarns Ti is formed of two adjacent half-layers that are offset with respect to one another in the warp direction. There are therefore 16 half-layers of weft threads positioned in staggered rows. Each chain wire Ci binds 3 half-layers of weft threads. It would also be possible to adopt a non-staggered layout in which the weft threads of two layers of neighboring weft threads are aligned on the same columns. By way of example, the fibrous texture according to the invention can be produced by 3D weaving according to an interlock weave as shown in FIG. 1 and with a warp and weft pattern of 8 threads / cm, 10 threads / cm and 12 threads / cm or with a thread count of 12 threads / cm and 5 threads / cm in weft. By "armor or multi-fabric fabric" is meant here a 3D weave with several layers of weft threads whose basic armor of each layer is equivalent to a conventional canvas type armor but with some points of the armor that bind the layers of weft threads together. FIG. 2 shows a multi-fabric web plane in which C2 warp yarns are occasionally deviated from their conventional 2D fabric path associated with a weft yarn layer CT2 to capture a weft yarn T2 of a adjacent layer and form particular PT fabric points binder two layers of neighboring weft son. At a particular fabric point PT, the warp thread C2 passes around two weft threads T2 located on the same column in two adjacent weft layers CT2. By way of example, the fibrous texture according to the invention can be produced by 3D weaving in a multi-fabric weave as shown in FIG. 2 and with a warp and weft structure of 20 threads / cm. By "multi-satin weave or fabric" is meant here a 3D weave with several layers of weft yarns whose basic weave of each layer is equivalent to a classic satin-like weave but with certain points of the weave which bind the layers of weft threads together. FIG. 3 shows a plane of a multi-satin fabric, in which each warp thread C3, with the exception of the warp threads situated on the textured surface, is deflected alternately in one direction and the other so as to seizing a weft thread T3 of n of a first layer CT3 of weft threads and a weft thread T3 of a second layer CT3 of weft threads adjacent to the first one, n being an integer greater than 2 realizing thus a connection between two layers.
    [0010] By way of example, the fibrous texture according to the invention can be produced by 3D weaving in a multi-satin weave as shown in FIG. 3 and with a warp and weft structure of 10 threads / cm.
    [0011] By "weave or multi-twill fabric" is meant here a 3D weave with several layers of weft threads whose basic armor of each layer is equivalent to a classic twill type armor but with some points of the armor that bind the layers of weft threads together. FIG. 4 shows a plane of a multi-twill fabric, in which each warp thread C4, with the exception of the warp threads situated on the texture surface, is deflected so as to grasp by 2 weft threads T4 of a CT4 layer of weft son or of several neighboring layers CT4 of weft son. By way of example, the fibrous texture according to the invention can be produced by 3D weaving in a multi-twill weave as shown in FIG. 4 and with a warp and weft context of 8 threads / cm. The yarns used to weave the fibrous texture intended to form the fibrous reinforcement of the piece of oxide / oxide composite material may in particular be formed of fibers consisting of one of the following materials: alumina, mullite, silica, an aluminosilicate , a borosilicate, or a mixture of several of these materials. Once the fibrous texture is achieved, it is compacted in order to adjust its fiber volume content to a value of between 40% and 51%. The compacting is carried out in a tool 100 which will be used for the deposition within the fibrous texture of refractory oxide particles as described below in detail. The compaction of the texture 10 is carried out by means of a grid 140 perforated so as to pass the slip used in the next operation. The grid 140 is held in abutment against the fibrous texture by wedging means, for example screws (not shown in FIG. 5), at a position in the tooling 100 corresponding to the compaction thickness Ec that the we want to apply to the texture. When there is no expansion of the fibrous texture after demolding (i.e. after APS impregnation and texture drying), the final thickness of the workpiece is equal to the compaction thickness Ec.
    [0012] The volume ratio of fibers corresponds to the volume fraction of the texture occupied by the fibers in the total volume of the texture produced. In the case for example of a fibrous texture having the shape of a flat plate, the following parameters are used to calculate the fiber volume ratio: length L of the texture, - width I of the texture, - thickness e of the texture, - density d of the fiber - surface mass Ms of the texture. Indeed, the volume content of fibers Tvf is equal to the volume of fibers Vf divided by the total volume of the texture. The volume of fibers used Vf is equal to the mass of fibers used, ie Ms.L.I, divided by the density of the fibers, ie: Vf = Ms.L.I / d.
    [0013] The total volume of the plate-like fibrous structure being equal to LIe, the fiber volume ratio Tvf is calculated with the following formula: Tvf = Ms / (ed) (1) Therefore, when it is desired to obtain a texture with a fiber content having a value between 40% and 51%, the compacting thickness of the fibrous texture is adjusted so that the latter has after compacting a thickness e which makes it possible to obtain a volume ratio of fibers between 40% and 51%, the compaction thickness being determined as a function of the surface density Ms of the texture and the density of the fiber as indicated by the formula (1). Refractory oxide particles are then deposited within the fibrous texture by the well known submicron powders (APS) aspiration technique. For this purpose and as illustrated in FIG. 5, a fibrous texture 10 made according to one of the 3D weaves defined above, is placed in an enclosure 110 of a tool 100. A filter 120 is previously interposed between the bottom 111 of the enclosure 110 and the fibrous texture 10, the bottom 111 having openings 1110. After placing the texture 10 in the enclosure 110, a slip 130, intended to allow the formation of a refractory oxide matrix in the texture, is deposited on the upper face of the fibrous texture 10, that is to say the face of the texture opposite to that facing the filter 120. The slip 130 corresponds to a suspension containing a submicron powder of particles of refractory oxide. The slurry 130 may for example correspond to an aqueous suspension consisting of alumina powder whose average particle size (D50) is between 0.1 μm and 0.3 μm and whose volume fraction is between 27% and 42%. the suspension being acidified with nitric acid (pH between 1.5 and 4). In addition to alumina, the refractory oxide particles constituting the submicron powder may also be made of a material chosen from mullite, silica, an aluminosilicate and an aluminophosphate. The refractory oxide particles may be further blended with zirconia, rare earth oxide or other fillers to add specific functions to the final material (carbon black, graphite, silicon carbide, etc.). ). After closure of the enclosure 110 by a cover 112, a gas flow Fi, consisting of compressed air or nitrogen, is introduced into the enclosure 110 via a conduit 1120. The stream Fi ensures the application of a 20 pressure Pi which forces the slip 130 to penetrate the texture 10. In combination with the introduction of the flow Fi, a pumping P, for example by means of a primary vacuum pump (not shown in Figure 5), is realized the outer side of the bottom 111 of the enclosure 110 through the openings 1110 so as to force the slip 130 to migrate through the texture 10. The filter 120 is calibrated to retain the refractory oxide particles present in the slip while the liquid of the latter is discharged through the openings 1110. The refractory oxide particles are thus deposited gradually by sedimentation in the texture.
    [0014] A fibrous preform loaded with refractory oxide particles is then obtained, in this case alumina particles of the type previously described. The preform is then dried at a temperature between 35 ° C and 95 ° C and then subjected to an air sinter heat treatment at a temperature of between 1000 ° C and 1200 ° C to sinter the refractory oxide particles together. and thus forming a refractory oxide matrix in the preform. This gives a piece of oxide / oxide composite material provided with a fiber reinforcement obtained by 3D weaving and which has no cracks in the matrix blocks present between the son of the reinforcement. FIG. 6 is a microscopic photograph of a section of a piece 200 of oxide / oxide composite material according to the prior art, namely here a reinforcement of alumina fibers densified by an alumina matrix and whose fibrous reinforcement 210 has was formed here by 3D weaving between layers of weft yarns 211 and warp yarns 212 in an interlock weave and with a warp and weft structure of 8 threads / cm and with a fiber volume of 38%. The piece 200 was manufactured in the same manner as described above, that is to say by APS followed by drying and sintering of the filled preform. As indicated in FIG. 6, the weave and the texture defined for the fibrous reinforcement 210 lead to forming blocks 220 of matrix 220 in the material which has, in at least one direction, a dimension which is greater than five times the maximum section of the reinforcement threads, here the section of a weft thread 211. As can be seen in FIG. 6, the limitation of the size of the matrix blocks to less than five times the maximum section of the reinforcement threads not being respected, cracks 230 have formed in the material. The presence of the cracks 230, some of which even cross threads of the reinforcement, significantly degrade the mechanical properties of the part 200. FIGS. 7A, 7B and 7C are microscopic photographs of a cut in the warp direction (the length of the photograph corresponding to the warp direction and the height of the photograph corresponding to the direction z) respectively of parts 300, 400, 500 each made of oxide / oxide composite material according to the invention, namely here a fiber reinforcement alumina densified by a matrix alumina . In FIG. 7A, the fibrous reinforcement 310 of the workpiece 300 has been formed here by 3D weaving between layers of weft threads 311 and warp threads 312 in a multisatin weave having a warp and weft thread count of 10 threads. cm and a fiber volume ratio of 43.4%. In FIG. 7B, the fibrous reinforcement 410 of the workpiece 400 has been formed here by 3D weaving between layers of weft threads 411 and warp threads 412 in an interlock weave having a warp thread count of 12 threads / cm and in weft 5 yarn / cm and a fiber volume of 44.8%. In FIG. 7C, the fibrous reinforcement 510 of the workpiece 500 has been formed here by 3D weaving between layers of weft threads 511 and warp threads 512 in an interlock weave having a warp and weft thread count of 12 threads. cm and a fiber volume ratio of 43.5%. Parts 300, 400 and 500 were manufactured in the same manner as described above, ie by APS followed by drying and sintering of the filled preform. The weave, the texture and the volume ratio of the fibers defined for the fibrous reinforcements 310, 410 and 510 lead to form blocks 321, 421 and 521 respectively of the matrix 320, 420 and 520 in the material which has, in any direction, a dimension which is less than five times the maximum section of the reinforcement yarns. As can be seen in FIGS. 7A, 7B and 7C, the limitation of the size of the matrix blocks to less than five times the maximum section of the reinforcement threads being respected, no crack is present in the material. Parts 300, 400 and 500 therefore have mechanical properties much greater than that of part 200. The table below gives the values obtained in terms of surface density Ms, plate thickness e, fiber density alumina) and Tvf fiber volume ratio for the pieces of FIGS. 6, 7A, 7B and 7C.
    [0015] 25 Piece Texture Ms (g / m2) e (mm) d TVf Piece 200 Interlock (Figure 6) 8/8 6667 4.5 3.9 38 Piece 300 Multisatin (Figure 7A) 10/10 5420 3.2 3.9 43.4 Part 400 Interlock (Figure 7B) 12/5 5420 5 3.1 3.9 44.8 Part 500 Interlock (Figure 7C) 12/12 5770 3.4 3.9 43.5 It can be seen that part 200 of Figure 6 is the only one that has a fiber volume ratio that is not between 40% and 51%. It is also noted that the piece 200 is the only one that has cracks in its material due to the presence of matrix blocks having at least in one direction, a dimension that is greater than five times the maximum section of the reinforcement threads. The method of the present invention makes it possible to manufacture oxide / oxide composite material parts from a three-dimensional woven fiber texture and APS which are perfectly homogeneous in their volume and which are devoid of cracks and porosities. These parts according to the invention have the following mechanical properties, measured in monotonic tension, at room temperature and in the warp direction: elastic modulus of between 120 GPa and 170 GPa, deformation with rupture at least equal to 0, 35%, - breaking stress greater than 250 MPa. Although the yarns of the 3D woven fiber reinforcement of the oxide / oxide material of a part according to the invention can be covered with an interphase, the process of the invention makes it possible to produce oxide / oxide composite parts with a fibrous reinforcement. woven 3D without interphase on the wires and, of course, without crack in the material.
    权利要求:
    Claims (7)
    [0001]
    REVENDICATIONS1. Part made of an oxide / oxide composite material comprising a fibrous reinforcement consisting of a plurality of layers of warp yarns and layers of weft yarn bonded together in three-dimensional weave, the spaces present between the reinforcement threads being filled by a matrix refractory oxide, characterized in that the fibrous reinforcement has a weave selected from one of the following armor: interlock, multi-fabric, multi-satin and multi-twill, and a warp and weft contexture between 4 and 20 son / cm, and in that the fiber reinforcement has a fiber volume of between 40% and 51%.
    [0002]
    2. Part according to Claim 1, characterized in that it has, in monotonic tension, at ambient temperature and in the warp direction: a modulus of elasticity of between 120 GPa and 170 GPa, a deformation with rupture at least equal to 0.35%, - a breaking stress greater than 250 MPa.
    [0003]
    3. Part according to claim 1 or 2, characterized in that the son of the fiber reinforcement are formed of fibers consisting of one or more of the following materials: alumina, mullite, silica, an aluminosilicate and a borosilicate.
    [0004]
    4. Part according to any one of claims 1 to 3, characterized in that the material of the matrix is selected from: alumina, mullite, silica, an aluminosilicate and aluminophosphate. 30
    [0005]
    5. A method of manufacturing a piece of oxide / oxide composite material comprising the following steps: - formation of a fibrous texture by three-dimensional weaving refractory oxide son, - compaction of said fibrous texture, 35 - placement of a side of the fibrous texture of a slurry containing a submicron powder of refractory oxide particles, establishing a pressure difference to force the slip to pass through the fibrous texture, - filtering of the slip liquid having passed through the fibrous texture for retaining the powder of refractory oxide particles within said texture, and - drying of the filled preform, - sintering of the submicron powder of refractory oxide particles to form a refractory oxide matrix in the preform , characterized in that, during the step of forming the fibrous texture, the yarns are woven according to a weave selected from one of the armu following interlock, multi-web, multi-satin and multi-twill, with a warp and weft pattern of between 4 and 20 threads / cm and in that, after the compaction step, said fibrous texture has a fiber volume content between 40% and 51%.
    [0006]
    6. A process according to claim 5, characterized in that the yarns of the preform are formed of fibers consisting of one or more of the following materials: alumina, mullite, silica, aluminosilicate and borosilicate.
    [0007]
    7. The method of claim 5 or 6, characterized in that the submicron particles are of a material selected from: alumina, mullite, silica, aluminosilicate and aluminophosphate.
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    法律状态:
    2015-02-25| PLFP| Fee payment|Year of fee payment: 2 |
    2016-02-09| PLFP| Fee payment|Year of fee payment: 3 |
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    申请号 | 申请日 | 专利标题
    FR1451447A|FR3017866B1|2014-02-24|2014-02-24|COMPOSITE OXIDE / REINFORCED OXIDE COMPOSITE MATERIAL AND MANUFACTURING METHOD THEREOF|FR1451447A| FR3017866B1|2014-02-24|2014-02-24|COMPOSITE OXIDE / REINFORCED OXIDE COMPOSITE MATERIAL AND MANUFACTURING METHOD THEREOF|
    US15/120,969| US10400367B2|2014-02-24|2015-02-19|Part made from oxide/oxide composite material for 3-D reinforcing and method for manufacture of same|
    EP15709280.0A| EP3110774B1|2014-02-24|2015-02-19|Part made from an oxide/oxide composite material for 3-d reinforcing and method for manufacture of same|
    CN201580008763.3A| CN106029607B|2014-02-24|2015-02-19|Component made of oxide/oxide composite material for 3-D reinforcement and method for manufacturing same|
    PCT/FR2015/050405| WO2015124872A1|2014-02-24|2015-02-19|Part made from an oxide/oxide composite material for 3-d reinforcing and method for manufacture of same|
    CA2939060A| CA2939060A1|2014-02-24|2015-02-19|Part made from an oxide/oxide composite material for 3-d reinforcing and method for manufacture of same|
    RU2016138073A| RU2681176C2|2014-02-24|2015-02-19|Part made from oxide/oxide composite material for three-dimensional reinforcing and method for manufacture of same|
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